Abstract
The reaction dynamics of methylene radical CH 2( X ̃ 3 B 1 ) with N 2O was investigated by time-resolved Fourier transform infrared spectroscopy. Pure CH 2(X̃ 3 B 1 ) radical was produced via laser photolysis of ketene at 351 nm. Nascent vibrationally excited products CO, NO and HCN were observed. Five reaction pathways and three possible reaction intermediates are proposed.
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