Abstract
The reactions of trans-M(OH)(CO)(PPh 3) 2 for M = Rh and Ir with CO 2 are described. The rate of reaction of Rh(OH)CO)(PPh 3) 2 in CH 2Cl 2 and in the presence of traces of water is first order in complex and independent of CO 2 and water concentrations. In the complete absence of water the reaction proceeds by a much faster pathway.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
