Abstract
2-Formylpyridine thiosemicarbazone (HFPT) reacts with the tin tetrahalides (X=Cl, Br, I) with abstraction of HX and the formation of tridentate N,N,S-bonded hexacoordinated species [SnX 3(FPT)]. A single crystal X-ray diffraction study of the chloro complex establishes mer-isomerism. Mössbauer data of the products correlate very well with a rehybridization of tin from sp 3 to d 2sp 3 upon complexation.
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