Abstract

In this work the scheme of the decomposition of alkaline metals solutions in liquid ammonia is proposed. On the basis of this scheme and by the means of fundamental laws of reaction kinetics (Guldberg-Waage's law and the principle of superposition for partial reaction velocities) a system of differential equations describing the course of decomposition of the mentioned solutions is set up and solved. By means of the found solution and on the basis of experimental data the rate constant characterizing the dissociation of liquid ammonia is estimated.

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