Abstract
The complex [Pt(cod)Cl(PMe 2Ph)]BF 4 reacts in dichloromethane with SnArMe 3 compounds having Ar = 2-thienyl, 2-benzol [ b]thienyl, or 2-benzo[ b]furyl to give air-stable cationic aryl complexes [Pt(cod)Ar(PMe 2Ph)]BF 4. No reaction takes place when Ar Ph. The cod ligand in the new complexes can be readily replaced by ligands such as PMe 2Ph, dppe, or 4-dimethylaminopyridine. The 1H and 31P-{ 1H} NMR parameters of the various complexes are reported.
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