The Rate-Determining Step of Electroadsorption Processes into Nanoporous Carbon Electrodes Related to Water Desalination

Abstract

Using potential perturbation techniques, we investigated the kinetics of electroadsorption processes of ions with different dimensions and different concentrations into activated carbon electrodes with various porous structures. We found that the ratio between the pore size and the ion size is of great significance in terms of electroadsorption kinetics. Microporous carbon fiber electrodes exhibited a lower charging rate as compared with mesoporous aerogel carbon. The use of activated aerogel electrodes with a fractal structure composed of both micro- and mesopores, was found to be the best for effective electroadsorption due to both high electrical double layer capacity obtained and high rates of electroadsorption. We also explored the kinetics of electroadsorption processes into molecular sieve carbon electrodes, demonstrating that, despite the hindered adsorption processes into these electrodes, it is possible to obtain effective deionization by using them for selective water desalination processes.