Abstract
Temperature dependence of the rate constant of the O (3 P ) + HCl → OH + Cl reaction was calculated for 200–700 K range within the quantum instanton approximation using the 3A″ potential energy surface. Curvature of the Arrhenius plot arising from quantum effects in the hydrogen exchange reaction was observed. Results of the present method were found to significantly improve upon those obtained within the ICVT/μOMT method. The errors pertaining to the present method were estimated.
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