Abstract
The high-pressure rate constant of the CF3 + CF3 → C2F6 reaction at T = 296 K was measured in the pulse photolysis (λ = 694.3 nm, ruby laser) of CF3NO in the presence of NO by means of the time-resolved detection of CF3NO by the intracavity absorption of He(SINGLE BOND)Ne laser radiation (λ = 632.8 nm). The obtained value is k2∞ = (3.9 ± 1.3) × 10−12 cm3/s. © 1996 John Wiley & Sons, Inc.
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