Abstract

The γ-radiolysis of hydrogen chloride in the presence of argon, krypton and xenon has been investigated. The experimental results have shown that the decomposition of hydrogen chloride in collision with the excited rare gas atoms is inefficient, most probably because excitation transfer occurs via (RHCl∗) complexes. Rate constant ratios of the collisional deactivation of these complexes have been evaluated. Reactions of the electron involved in the Xe-HCl system are discussed. It has been found that only part of the thermal electrons captured by HCl forms H 2 as a final product.

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