Abstract

The intercalation of organotin-compounds into laponite and the formation of tin(IV) oxide pillars is rapidly achieved when performed in a microwave oven.119Sn Mossbauer- and x-ray- photoelectron-spectroscopy suggest that Ph3SnCl and Ph2SnCl2 undergo hydrolysis on the surface once sorbed. The treatment of Ph3SnCl/laponite with microwave radiation also induces the formation of a metallic phase which contains both tin and magnesium.

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