Abstract

Low temperature crystallography (150 K) has been used to confirm that the two extreme [Cu (chelate) 2Cl] [Y] stereochemistries of 3 [Cu (bipy) 2Cl] [PF 6]·H 2O, trigonal bipyramidal and 6 [Cu (phen) 2Cl] [BPh 4], trigonal bipyramidal distorted square based pyramidal, are genuine and static stereochemistries of the copper (II) ion.

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