Abstract

The pure rotational and rotation-vibrational Raman spectrum of oxygen gas at 1 atmosphere pressure has been photographed under high dispersion in the first order of a 15,000 lines/inch, 21-foot concave grating in Wadsworth mounting. The molecular constants are δ ν0=δG 1 2 =1556.26, B e=1.4457, α=0.0158, D 0=D ν=5.6 × 10 −6 cm −1 These results are in good agreement with those obtained from the study of the electronic spectrum.

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