Abstract
The Raman spectra of water, heavy water D2O and ice have been studied using the λ2537 radiation of the mercury are as exciter. The shifts observed in water are Δν=60, 175, 475, 758, 1630, 3260, 3426, and 3610 cm.−1 Heavy water exhibits Raman bands at Δν=60, 176, 300–450, 1207, 2373, 2539 and 2670 cm.−1 The band at 60 cm.−1 is reported for the first time. A new Raman band is observed in the spectrum of ice extending from 213–310 cm.−1, the other Raman lines being at 52, 213·1, 3147, 3264 and 3347 cm.−1
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