The Raman signature of H2 in the uv spectra of Uranus and Neptune: Constraints on the haze optical properties and on the para-H2 fraction

Abstract

The geometric albedos of Uranus and Neptune, inferred from archived Hubble Space Telescope observations and from the ground-based measurements of Karkoschka, 1994, are modeled in the wavelength range 2200–4200 Å. The radiative transfer model, which includes Rayleigh–Raman scattering and Mie scattering by haze particles, aims at reproducing the fine structure of the geometric albedos at a resolution of 2–10 Å. The steep variation of the total optical depth allows to investigate the influences of both the stratospheric and tropospheric haze layers and that of the deep tropospheric cloud, although their relative importance is difficult to estimate accurately. Using the haze models of Baines et al., 1995, the optical properties of the Mie scatterers are inferred. The haze material on Uranus is characterized by a slowly decreasing imaginary index of refraction: ni varies from about 0.10 to 0.01–0.02 between 2200 and 4200 Å. Below 3000 Å, the absorptivity of Neptuness haze material is comparable to that on Uranus or slightly lower (ni ∼ 0.03–0.10). Above 3000 Å, it exhibits a steeper decrease (from 0.30 to 0.003). The main source of uncertainty at longer wavelengths is the reflectivity of the underlying (H2S ?) cloud. At shorter wavelengths, molecular scattering strongly dominates Mie scattering and the determination of the absorptivities is estimated to be accurate within a factor of 2. For Neptune, there is an additional uncertainty due to the inability of the initial haze model to provide a fit to the observed albedo. The Baines et al. model was modified by multiplying the number-densities of the hydrocarbons haze layers by a factor of 2.5–4.8, making it more consistent with the results of Pryor et al., 1992. For Uranus, these results suggest a darkening of the southern hemisphere since the Voyager epoch, in agreement with recent HST imaging. As a whole, the Neptunian haze seems to be more transparent than that of Uranus, possibly owing to the more turbulent dynamical state of the troposphere. Longwards of 3000 Å, the inferred absorptivities are consistent with laboratory measurements on tholins produced from CH4–H2 gas mixtures (Khare et al., 1987). The para-H2 mole fraction on both planets is constrained from the strength of a prominent H2 Raman feature at 2853 Å. On Uranus, at latitudes between 45 and 75°S and in the 50–500 mbar pressure range, the best agreement is obtained with an equilibrium para-H2 distribution. On Neptune, there is an indication of a slight departure from equilibrium in the same pressure range at mid-southern latitudes. Although this new method is significantly less accurate, its results are consistent with those of previous investigations based on the analysis of H2 quadrupole lines (Baines et al., 1995) and of the Voyager IRIS spectra (Conrath et al., 1998).