Abstract

Laser induced fluorescence has been observed from the B3Π(O+u) state of chlorine. Lifetimes have been measured from 19 to 208 Pa, but the radiative lifetime is too long to be extracted from the data. A rate coefficient of 3.2 × 10[su13] cm3 mol−1 s−1 was measured for quenching by Cl2 or Ar, the removal process being collision induced predissociation of the 3Π(O+u) state.

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