Abstract

The PMR spectra of a series of benzyltin compounds (C 6H 5CH 2) nSnX 4-n ( I⪡ n⪡4, X=H, Cl, Br, I, OCOCH 3) have been studied. Evidence is presented that substituents X equally influence all the ring protons chemical shifts and this is ascribed to changes in the π-electron system of the ring. The methylene group shifts are the result of ring current, inductive effect and diamagnetic anisotropy contributions. The coupling constants J(Sn-C-H) cannot be interpreted by changes in s electron density around the tin atom only.

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