Abstract

AbstractCertain metal ions are shown to influence the enzymic hydrolysis of maize starch. Amyloglucosidase was not affected by the metal ions but á‐ and ß‐amylase were affected by varying degrees. Calcium ions produced a positive effect with both fungal and bacterial α‐amylases but no effect with ß‐amylase, whilst zinc, ferric and lead ions produced negative effects or no effect. A simultaneous enzymic hydrolysis (using α‐ and ß‐amylases) and catalytic hydrogenation showed enzyme inhibition by the nickel catalyst. High hydrogen pressure (100 at) had little effect on the enzymes. The hydrolysis and hydrogenation of the starch fraction of milled whole defatted maize was also shown to be feasible.

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