Abstract
The process of forming (2223) phase was studied by x-ray diffraction, thermal analysis, as well as electric and magnetic measurements. It was discovered that the formation of (2223) from (2212) is a phase transition-like process. Some possible mechanisms of (2212) to (2223) phase transition-like are discussed. Our results not only explain the difficulty for getting pure (2223) phase sample, but also give a way to prepare high quality (2223) phase sample.
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