The Problem of the Top Cell for the Micromorph Tandem

Abstract

ABSTRACTA detailed study of the influence of different materials for the amorphous top cell on the stabilized efficiency of amorphous silicon/microcrystalline silicon (”micromorph”) tandem cells is presented. The authors investigate different amorphous i-layer materials which are applied in cells with varying thicknesses. It is shown that it is preferable to optimize the top cell in order to obtain a high current rather than a high voltage.A simple optical and electrical model is presented which allows one to predict the optimum optical bandgap of the i-layer material of the top cell and to determine its optimum thickness for maximum stabilized efficiency. By means of this model it is shown that the optimum top cell for a total cell current of 26 mA/cm2 should contain an about 2500 Å thick i-layer with an optical gap Eo4 ≃ 1.8 eV. The model furthermore shows that it is desirable to obtain slightly bottom-limited conditions after degradation in order to maximize the output power.A stabilized efficiency of 10.7 % for a micromorph tandem cell has been confirmed by an independent measurement (FhG-ISE). Another such cell yields a stabilized efficiency of 11.2 % as measured in our laboratory.