Abstract

This review has four major objectives: I) to present the problem of phthalate pollution, II) to highlight common techniques for quantification of phthalate compounds in <br /> water, III) to summarize current trends in determination of phthalates toxicity and point <br /> out the major adverse effects, and IV) to discuss and critically compare modern approaches in purification of phthalate-polluted water samples and thus reveal the further <br /> perspectives. Phthalates are organic compounds that are used extensively as additives in <br /> plastics and personal care products. They have high leaching potential and, therefore, <br /> they have been detected in various environments, including aquatic environments. Concentrations of phthalates in water are generally low, so their determination usually requires preconcentration. However, phthalates are compounds with very high hazardous <br /> potential. Related toxicity studies have been focused mainly on long-term exposures, and <br /> the results have shown that phthalates mainly affect the endocrine and reproductive systems. Therefore, phthalates have become a global concern. Their removal from the environment not only ensures environmental protection, but the protection of human health as well. Among various presented approaches for phthalates removal, anaerobic biodegradation has shown the highest potential for further developments because it is a promising technology for using wastewater as a source of green energy.

Highlights

  • The industry of plastics production is increasing constantly

  • Related toxicity studies have been focused mainly on long-term exposures, and the results have shown that phthalates mainly affect the endocrine and reproductive systems

  • These additives can be generally divided into two major categories: those that modify physical characteristics of the polymer, and those that have a preventive effect on ageing and degradation of the material.[5]

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Summary

Introduction

The industry of plastics production is increasing constantly. A production of 265 million tons was reported in 2010, four years later it reached 310 million tons, while in 2019, it exceeded 368 million tons.[1,2,3] This is not surprising knowing that plastic products have become an inevitable part of human daily routine. Various additives are added to the polymer base during plastics production to facilitate the molding process or to enhance some specific product characteristics.[4] These additives can be generally divided into two major categories: those that modify physical characteristics of the polymer (e.g., plasticizers, fillers, colorants, lubricants, foam­ ­ing agents...), and those that have a preventive effect on ageing and degradation of the material (e.g., flame retardants, antistatic agents, biocides, UV stabilizers, antioxidants...).[5] Plasticizers are additives

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