Abstract

The theoretical and experimental aspects of the specific heats of solids, liquids and gases in the light of present knowledge are discussed. Possible lines of advance have been indicated for solids in view of the progress now being made in X-ray crystallography, and the importance of further experimental work on compressibilities and elastic constants is suggested. Tentativeviews on the specific heat of liquids are given. In gases the quantum theory of rotational heat is shown to fail to account satisfactorily for the behaviour of hydrogen at low temperatures. The chemical constant of monatomic and diatomic substances is discussed, both from a thermodynamic and from a statistical point of view. Current views on the nature of this constant are described. The theory of gaseous degeneracy and its bearing upon specific heats and chemical constants is reviewed.

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