Abstract

The synthesis of high-purity tin(II) bromide from the elements is detailed. The vapour pressure above the liquid phase has been measured by the quasistatic method over the temperature range 576 K to 923 K and the molar enthalpy of evaporation calculated by the second-law and third-law methods. Previously reported values for the molar enthalpy of formation, melting temperature, molar enthalpy of fusion, and molar heat capacities are reviewed and critically assessed. A comprehensive set of thermodynamic quantities for tin(II) bromide is presented.

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