Abstract
The tetracyanonickelates Ni(NH3)2Ni(CN)4·1.9 H2O (1), Ni(NH3)1.65(C4H8O2)0.2Ni(CN)4·0.8 C4H8O2·0.35 H2O (2) and Ni(en)3Ni(CN)4·H2O (3) exhibit, after contact with a solution of iodine (I2/KI), appreciable weight gains. According to thermal analysis, IR spectra and chemical analysis the new products contain intercalated iodine and iodides with the highest iodine content found in the product formed from (3). The results of high frequency conductance measurements of this product showed the highest value of electrical conductivity σ (10−6 S cm−1). Other compounds show relatively low values of σ (10−8–10−11 S cm−1).
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Journal of Inclusion Phenomena and Molecular Recognition in Chemistry
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
