Abstract
The tetracyanonickelates Ni(NH3)2Ni(CN)4·1.9 H2O (1), Ni(NH3)1.65(C4H8O2)0.2Ni(CN)4·0.8 C4H8O2·0.35 H2O (2) and Ni(en)3Ni(CN)4·H2O (3) exhibit, after contact with a solution of iodine (I2/KI), appreciable weight gains. According to thermal analysis, IR spectra and chemical analysis the new products contain intercalated iodine and iodides with the highest iodine content found in the product formed from (3). The results of high frequency conductance measurements of this product showed the highest value of electrical conductivity σ (10−6 S cm−1). Other compounds show relatively low values of σ (10−8–10−11 S cm−1).
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