Abstract
Reactive 1,6-disubstituted perfluorohexanes have been prepared via the reaction of 1,6- bis (dimethylhydrosilyl)-perfluorohexanes with alkyllithium and Grignard reagents. The resulting species may be derivatized in the same manner as organolithium reagents, but are appreciably more stable than the 1,6-dilithioperfluorohexane which is presumably generated by the halogen-metal exchange between an alkyllithium reagent and Br(CF 2) 6Br. 1,6-bis(Bromomagnesium)-perfluorohexane was also prepared in good yield by a halogen-metal exchange reaction.
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