Abstract
Abstract The preparations of cis - and trans -[PtH(C 6 Cl 5 )(PEt 3 ) 2 ] by thermal decomposition of cis - and trans -[Pt(OCHO)(C 6 Cl 5 )(PEt 3 ) 2 ], respectively, are reported. Also described are cis - and trans -[Pt(SnCl 3 )(C 6 Cl 5 )(PEt 3 ) 2 ], obtained by treating SnCl 2 with cis - and trans -[PtCl(C 6 ,Cl 5 )(PEt 3 ) 2 ], respectively. It is shown that while trans - [PtH(C 6 Cl 5 )(PEt 3 ) 2 ] does not form hydride-bridged complexes in the presence of trans -(PtH(MeOH)(PEt 3 ) 2 ] + , the corresponding complex trans -[PtH(C 6 )(PEt 3 ) 2 ] reacts with the same solvento complex, in methanol, giving labile [(PEt 3 ) 2 HPt(-μH)Pt(C 6 F 5 )(PEt 3 ) 2 ] + .
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