Abstract

A space precipitation diagram of [Ce]‐[O]‐[S] in pure liquid iron has been constructed utilising recent experimental thermodynamic data gathered on allied equilibrium systems of RE‐O, RE‐S and RE‐O‐S. A quantitative correlation between the activities of oxygen, sulphur and the constitution of the formed RE inclusions has been found. This correlation was theoretically evaluated through thermodynamic calculation and verified by experimental data concerned with the activities of oxygen and sulphur in liquid iron and the composition of the formed RE inclusions.

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