Abstract
A chlorination of optically active alkyl p-tolyl sulfoxides with N-chlorosuccinimide in dichloromethane in the presence of potassium carbonate afforded optically active 1-chloroalkyl p-tolyl sulfoxides in 87–94% ee (88–94% chemical yields). The optically active chloroalkyl sulfoxide was applied to a synthesis of optically active (+)-disparlure.
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