Abstract
The present work investigated the potential of using zeolite (clinoptilolite), montmorillonite (Swy2), and Conocarpus biochar as adsorbents to remove 226Ra from aqueous solution. The effect of the initial 226Ra concentrations on sorbents’ equilibrium activity concentrations and sorbents’ radium removal efficiency were investigated. The results showed that zeolite has a higher removal efficiency for 226Ra in comparison with the efficiencies of montmorillonite and biochar. In addition to the linear isotherm model, the Freundlich model, followed by Temkin’s model, provided a better description of the adsorption process than the Langmuir model. Kinetic studies indicated that a pseudo-second-order kinetic model could be the best fit for the adsorption of 226Ra onto the three investigated sorbents, which suggests that the mechanism of adsorption of 226Ra by sorbents was chemisorption. The intraparticle diffusion model indicated that adsorption of 226Ra onto the sorbents involves a multistep process: (i) boundary layer diffusion and (ii) intraparticle diffusion. Moreover, the remediation of groundwater samples polluted with 226Ra was assessed using the investigated sorbents; the results showed that zeolite also has the highest removal efficiency among other sorbents. Thus, the low cost, availability, and the high adsorption efficiency of zeolite can be a promising sorbent on 226Ra removal from aqueous solutions and groundwater remediation.
Highlights
In a broad sense, water resources have been subject to pollution from the increases in concentrations of both heavy metals and natural radionuclides
The results show that adsorption of 226 Ra by zeolite, montmorillonite, and biochar tended to increase by increasing the initially added activity concentrations of 226 Ra
It was observed that the adsorption of 226 Ra onto zeolite shows a different behavior than its adsorption onto montmorillonite and biochar
Summary
Water resources have been subject to pollution from the increases in concentrations of both heavy metals and natural radionuclides. Radium is considered one of the most naturally occurring radionuclides that exist in appreciable amounts in water and groundwater in particular. Water hosted within igneous rocks has a higher radium concentration than those hosted within sedimentary rocks [1,2]. Human activities can result in the elevation of radium in the environment, which reaches surface water and groundwater. Such activities include the production of the oil and gas industry [3,4], uranium mining [5], and phosphate fertilizers [6]
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