The Potential Significance of Microwave-Assisted Catalytic Pyrolysis for Valuable Bio-Products Driven from Albizia Tree

Abstract

The objective of this study is to investigate the feasibility of Na2CO3 and ZSM-5 as catalysts in the microwave pyrolysis of Albizia branches. An evaluation was conducted to determine the influence of power applied, experimental time, particle size, and catalysis type and ratio on the quality and quantity of pyrolysis products. Established methods such as GC-MS, FTIR, HHV, SEM, EDX, and BET were used to characterize the properties of bio-oil and biochar produced. The results demonstrated that using both catalyst types led to a substantial enhancement in biogas production. The improvement ranged from 5% to 41% with Na2CO3 and reached 45% with ZSM-5. At a lower power level of 300 W, the bio-oil yield augmented from 28% to 40% and 53% when using ZSM-5 and Na2CO3, respectively. The GC-MS analysis revealed that the utilizing of catalysts enhanced the levels of aromatic compounds, esters, and alcohols in bio-oil, along with an increase in the higher heating value (HHV) from 19.5 MJ/kg to 22 MJ/kg and 24.2 MJ/kg using Na2CO3 and ZSM-5, respectively. Moreover, the biochar's surface area and pore volume experienced a considerable rise, going from 0.5512 m2/g and 0.00011 cm3/g to a higher value of 115.2073 m2/g and 0.0774 cm3/g when treated with Na2CO3. The data indicated that both catalyst types enhanced the generation of CH4, and CO2 was lower with ZSM-5. The utilization of catalysts improves the quality of the biofuel produced and promotes the efficiency of the process in terms of energy consumption and processing time.