Abstract
AbstractThe influence of solid surfaces on the polymerization of diacetylenes has been studied using 3,5‐octadiyn‐1,8‐diol as a model compound. The first molecular layers on polar surfaces are adsorbed by hydrogen bonds. Their relative orientation hinders the polymerization of these molecules. Subsequent layers can be polymerized by UV radiation. After the unreacted monomer has been extracted a highly stable polymer film remains on the surface.
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