The physicochemical and thermophysical properties of sodium dodecyl sulfate: The influence of p-toluene sulfonyl chloride and temperature

Abstract

In the present study, we report on the interaction between a hydrotrope, p-toluene sulfonyl chloride (p-TSC), and an anionic surfactant, sodium dodecyl sulfate (SDS) which has been performed using electrical conductivity, Fourier transform infrared (FTIR), 1H NMR, density, dynamic viscosity, and kinematic viscosity measurements. The effect of p-TSC on the micellization of SDS in non-aqueous (ethanol) medium at various temperatures (viz., 298.15, 303.15, 308.15, 313.15, 318.15, and 323.15 K) was investigated using the electrical conductivity method. The results show that the CMC value increases as the concentration of the hydrotrope is increased. It is noteworthy that at higher concentrations of hydrotrope, the trend of micelle formation is reversed (i.e., reverse micelles are formed). The thermodynamic parameters in micellization have also been evaluated. The FTIR and 1H NMR data reveal the physicochemical properties of the pure and mixed systems and confirm no covalent bond formation takes place. Density, dynamic viscosity, and kinematic viscosity of the pure as well as mixed systems at various temperatures were also reported.