Abstract
Previous results concerning the photolysis of [MN(C 2O 4) 3]K 3 and trans-[Mn(C 2O 4) 2(H 2O) 2K in dimethyl formamide together with recent flash photolysis data on the substituted complex are used in the development of a general photolysis mechanism which shows some differences from earlier models. This mechanism involves processes that can be treated using Noye's concept of geminate recombination and enables the rate constants and quantum efficiencies of primary processes such as internal conversion and ligand-to-metal charge transfer to be estimated. These data are consistent with structural predictions.
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