Abstract
Benzoyl-carbazole and its derivatives are considered a platform for exploring processes such as room temperature phosphorescence (RTP) and thermally activated delayed fluorescence (TADF). They have also been reported to exhibit dual emission, but there is a great spectral variability in the relative intensity of the emission bands reported in different studies. To better understand the fundamental photophysical properties, we set to explore BCz and its perfluorinated derivative F5BCz using spectroscopy and quantum chemical simulations. We find that the reported dual fluorescence in solution and in films results from a photochemical process (photo-Fries rearrangement), producing carbazole among other products, explaining the variation in the reported emission spectra. In addition, BCz exhibits solvent dependent TADF, which is explained by the stabilization of the charge transfer S1 state in polar solvents. F5BCz undergoes an efficient photochemical process (Mallory reaction) from its single state to produce highly fluorescent product c-F5BCz, in 40% isolated yield. This photoreactivity also proceeds in films under ambient conditions, which have significant implications on the applications of BCz-based materials for optoelectronic applications.
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