Abstract

The photolysis of bis aryl-1,3 triazenes carried out in non-aromatic solvents gives products whose structures are consistent with a cage recombination process of homolytically formed radicals and the subsequent abstraction of hydrogen from the solvent molecules by these arylamino radicals. In aromatic solvents, a free-radical chain process leads to the formation of products resulting from the homolytic substitution on the solvent.

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