The phase structure and electrical performance of the limited solid solution CuFeO2–CuAlO2 thermoelectric ceramics

Abstract

The limited solid solutions of nominal (1 − x) CuFeO2 − xCuAlO2 have been prepared by conventional solid-state reaction, and thermoelectric property has been measured. From the XRD powder pattern, we found that the major phase of the limited solid solution is rhombohedral delafossite structure when the composition is near the end members. Cubic Cu(Fe,Al)2O4 phase has been formed in composition from x = 0.4 to 0.8. Electrical resistivity of samples with major delafossite structure is lower than that of samples with Cu(Fe,Al)2O4 phase. In the zone of phase transform, the electrical resistivity can be got with lower value, such as x = 0.2, 0.3 and 0.9. The Seebeck coefficient for the limited solid solution with delafossite structure is positive in whole measured temperature range from 300 to 923 K. In the end, the power factor for the limited solid solution with major delafossite structure shows higher value, which is resulted from the lower electrical resistivity by the phase transposition. The highest power factor of 1.14 × 10−4 W/mK2 has been addressed at 907 K for x = 0.2, which value is enhanced by 3–4 times than that of pure phase CuFeO2 or CuAlO2.