The phase dynamics and wetting layer formation mechanisms in two-step surface-directed spinodal decomposition

Abstract

The two-step quench process of surface-directed spinodal decomposition is numerically investigated by coupling the Flory-Huggins-de Gennes equation with the Cahn-Hilliard-Cook equation. The phase dynamics and formation mechanisms of the wetting layer in two-step surface-directed spinodal decomposition have been concerned in detail. The results demonstrate that a parallel strip structure forms near the wetting layer and propagates into the bulk, when the first quench depth is very shallow and the bulk does not undergo phase separation, and the second quench depths are various points with deeper quench depths. In this case, the wetting layer turns to be unchangeable at the intermediate and later stages of the second quench process, compared to the growth with a time exponent 1/2 during the first quench process. When the first quench depth is deeper and phase separation occurs in the bulk during the first quench process, it is found that a deeper second quench depth can stimulate a more obvious secondary domain structure, and the formation mechanism of the wetting layer changes from logarithmic growth law to Lifshitz-Slyozov growth law.