Abstract
The quasibinary system Hg3Se3/Ga2Se3 was investigated by X-ray phase analysis and by DTA. The system forms extended regions of solid solutions with zincblende structure. Moreover, it shows at several distinct stoichiometries the formation of superstructures. The phase diagram of this system can be modeled by a Gibbs energy function for a sub-regular system including ordering terms. The thermodynamic factor for interdiffusion was calculated from the excess Gibbs energy function.
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