Abstract
The antibiotic, flambamycin, is shown to have the novel oligosaccharide structure (1) associated with two orthoester linkages. It is proposed that flambamycin (1), the everninomicins (28), curamycin, avilamycin, destomycin A (29a), destomycin C (29b), destomycin B (30), hygromycin B (29c), the antibiotics A-396-I (29d) and SS-56C (29e), belong to a new family of antibiotics called the orthosomycins.
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