Abstract
Gold catalysts have found applications in many reactions of both industrial and environmental importance. Great interest has been paid to the development of new processes that reduce energy consumption and minimize pollution. Among these reactions, the catalytic oxidation of carbon monoxide (CO) is an important one, considering that a high concentration of CO in the atmosphere creates serious health and environmental problems. This paper examines the most important achievements and conclusions arising from the own authorship contributions concerning (2 wt. % Au)/Ce1−xZrxO2 catalyst’s active sites in low-temperature CO oxidation. The main findings of the present review are: (1) The effect of preparing conditions on Au crystallite size, highlighting some of the fundamental underpinnings of gold catalysis: the Au surface composition and the poisoning effect of residual chloride on the catalytic activity of (2 wt. % Au)/Ce1−xZrxO2 catalysts in CO oxidation; (2) The identification of ion clusters related to gold and their effect on catalyst’ surface composition; (3) The importance of physicochemical properties of oxide support (e.g., its particle size, oxygen mobility at low temperature and redox properties) in the creation of catalytic performance of Au catalysts; (4) The importance of oxygen vacancies, on the support surface, as the centers for oxygen molecule activation in CO reaction; (5) The role of moisture (200–1000 ppm) in the generation of enhanced CO conversion; (6) The Au-assisted Mars-van Krevelen (MvK) adsorption–reaction model was pertinent to describe CO oxidation mechanism. The principal role of Au in CO oxidation over (2 wt. % Au)/Ce1−xZrxO2 catalysts was related to the promotion in the transformation process of reversibly adsorbed or inactive surface oxygen into irreversibly adsorbed active species; (7) Combination of metallic gold (Au0) and Au-OH species was proposed as active sites for CO adsorption. These findings can help in the optimization of Au-containing catalysts.
Highlights
It is a great pleasure and honor for us to contribute to this Special Issue of the Catalysts journal dedicated to recognizing the outstanding career contributions of Professor Hugo de Lasa to the fields of heterogeneous catalysis, photocatalysis and catalytic reaction engineering
Since our earlies work [21,24], we have demonstrated the effectiveness of CeO2 –ZrO2 mixed oxides used as supports for Au nanoparticles in low-temperature carbon monoxide (CO) oxidation
The most important achievements and conclusions arising from the own authorship contributions concerning (2 wt. % Au)/Ce1−x Zrx O2 catalyst’s active sites in low-temperature CO oxidation were reviewed
Summary
It is a great pleasure and honor for us to contribute to this Special Issue of the Catalysts journal dedicated to recognizing the outstanding career contributions of Professor Hugo de Lasa to the fields of heterogeneous catalysis, photocatalysis and catalytic reaction engineering. The interest in studying supported gold catalysts has increased since Haruta and coworkers discovered their extraordinary activity for low-temperature CO oxidation [6]. Metal-support interactions have a significant effect on the performance of supported gold catalysts Their efficiency in CO oxidation at low temperatures depends on various factors, including the nature of the support, Au particle size, preparation procedure, pretreatment conditions and properties of the gold-support interface. The last group of topics is related to unveil the mechanism of catalytic CO oxidation This reaction is considered as a relatively simple one, over 20 different mechanistic steps are proposed in the open literature [32,33,34,35,36,37,38].
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