Abstract
Transitions between Rydberg states of atomic chlorine have been detected between 1477 and 1507 cm-1 by the technique of carbon monoxide laser magnetic resonance (LMR). Transitions have been observed in both emission and absorption. The spectra have been assigned for those transitions involving levels which have been identified previously. However, several more resonances are unassigned, revealing the presence of previously unidentified states of atomic chlorine. Many of the lines show resolved nuclear hyperfine structure.
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