Abstract
Computer simulations of the n-heptane+perfluoro-n-hexane system is used to understand the unusual behaviour of the horizontal inflection of the vapour–liquid interfacial tension experiments of alkanes–perfluoroalkanes mixtures. Simulations are conducted and good agreement with experiments is obtained. From the results a change in curvature to a nearly constant value in the tensions at high perfluoro-n-hexane compositions is identified. Dynamic, thermodynamic and structural properties are analysed in that region and peculiar tendencies of those properties are found which help us to understand the nature of the uncommon inflection in the isotherms.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
