Abstract

Time-resolved laser-induced fluorescence detection of metastable and NO and time-resolved emission spectroscopy of the -band of NO have been applied to a - RF pulsed discharge in order to show that the process is responsible for NO(A) excitation in discharge systems of this kind. Highly resolved spectra obtained under such conditions have revealed that there is a non-Boltzmann rotational distribution in the ) state with a large excitation of levels J>20.

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