Abstract
The high concentration and fast accumulation of sulfate have been identified in most of the haze episodes’ events. It is well known that the autoxidation process is one of the most common and essential routes for sulfate formation. However, the detailed mechanism underlying sulfate formation, especially that from oxygen (O2) involved autoxidation process, has not been fully established since there is no direct experimental proof available till now. In this work, we thoroughly explored the possible sulfate formation pathways involving O2 through high-level quantum chemical calculation investigation. It is revealed that in the autoxidation process, the reaction of SO3− with O2 will occur on the doublet potential energy surface to form SO5−. We further proposed a pH dependent reaction mechanism in which SO5− will react with different forms of SO2 (HOSO2−, SO32−) through four different pathways to produce sulfate. More importantly, by calculating the branching ratios for different pathways, we found the most dominant path involving O2 in sulfate formation in almost all the atmospherically relevant pH during pollution period. In this path, SO5− react with SO32− through two steps: a O atom transfer process and a subsequent single electron transfer (SET) process. Detailed calculation results emphasize the importance of autoxidation mechanism in explaining sulfate formation during pollution period, and therefore provide some important and detailed information for understanding the possible reason of haze episode.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.