The nature and stability of aluminum hydroxide precipitated on wyoming montmorillonite

Abstract

A freeze—fracture technique was used to prepare replicas of interlayer surfaces of a hydroxy-aluminum montmorillonite (OH-Al-SWy-1), synthesized by titrating an Al-clay with NaOH. Aqueous suspensions containing 0.01 M NaClO 4 and 4% OH-Al-SWy-1 were frozen rapidly with Freon 22 to vitrify the solution phase and stored in liquid N 2. The frozen samples were fractured at 10 −6 Torr and 158K and C-Pt replicas were made of the exposed surface. Transmission electron microscopy (TEM) of the replicas showed a randomly distributed surface precipitate. The precipitate was flat and angular, resembling gibbsite morphologically. Gibbsite crystals were observed outside the interlayer when the suspension was air-dried on microscope grids, underscoring the value of the freeze—fracture technique in minimizing alteration of the OH-Al-SWy-1 complex. Using the mass of Al(OH) 3 fixed by the clay and the average particle perimeter observed by TEM (49.3 nm), we estimated the maximum Al(OH) 3 surface charge density and site density available for phosphate adsorption. The range of surface charge density for the Al(OH) 3, estimated from crystallographic data, was very close to the range of surface charge density for montmorillonite, suggesting that the latter may influence the maximum particle size of the precipitate. The total charge and edge [-Al(OH)(H 2O)] site density were less than the observed CEC reduction on SWy-1 and maximum phosphate retention on OH-Al-SWy-1 at pH 5.3, respectively. Interlayer Al(OH) 3 is known to be unstable with respect to gibbsite and it is possible that a relatively high specific surface area was responsible for the high solubility.