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Abstract
The structure of Nasicon-type copper(I) titanium phosphate CuTi 2(PO 4) 3 has been investigated by neutron diffraction. The copper environment is a compromise between the usual linear coordination of copper(I) and the octahedral surrounding of the M(1) site within the 3-D [Ti 2(PO 4) 3] skeleton. Preliminary results concerning the various mechanisms able to lead to the redox reaction Cu 2+ + e − → Cu + are reported.
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