Abstract
AbstractA series of salts that contain the terphenyl‐substitutedbis(amino)phosphenium cation with different anions (F–,Cl–, [CF3CO2]–, [CF3SO3]–, [B(C6F5)4]–, [GaCl4]–, [SbF6]–, [Al{OCH(CF3)2}4]– and [CHB11H5Br6]–) has been prepared by different synthetic protocols. All of the products have been characterised spectroscopically and by single‐crystal X‐ray diffraction studies. A detailed analysis of the interionic interactions and their influence on the molecular structure of the phosphenium cation reveals a strong dependence on the capability of the anion to enter the pocket generated by the bulky terphenyl substituents.
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