Abstract

AbstractInterfacial bonding between the fibers and matrix plays a large role in mechanical properties of composites. In this paper, poly(oxypropylene) diamines (D400) and graphene oxide (GO) nanoparticles were grafted on the desized 3D multi axial warp knitted (MWK) glass fiber (GF) fabrics. The surface morphology and functional groups of modified glass fibers were characterized by scanning electron microscopy (SEM) and fourier transform infrared spectra (FT-IR). Out-of-plane compression properties and the failure mechanisms of composites at different temperature were tested and analyzed. The results revealed that GO nanoparticles were successfully grafted on fibers under the synergistic effect of D400. In addition, D400-GO-grafted composite possessed the highest mechanical properties than desized composite and GO-grafted composite. Their strength and modulus were improved by 10.16%, 10.06%, 8.92%, 8.75%, 7.76% and 40.38%, 32.74%, 29.85%, 26.98%, 25.16% compared to those of desized composites at 30∘C, 60∘C, 90∘C, 120∘C, 150∘C, respectively. The damage to D400-GO-grafted composite was yarns fracture accompanied with fibers breakage, matrix cracking, interface debonding. At higher temperature, interlayer slipping with matrix plasticization was the main failure mode.

Highlights

  • Interfacial bonding between the fibers and matrix plays a large role in mechanical properties of composites

  • Poly(oxypropylene) diamines (D400) and graphene oxide (GO) nanoparticles were grafted on the desized 3D multi axial warp knitted (MWK) glass fiber (GF) fabrics

  • Comparing with desized GF, peaks at 1417 cm−1 of C=O stretching, 1044 cm−1 of C-O stretching were obvious for D400-GO-grafted fabrics and GO-grafted fabrics, which demonstrated that GO was successfully grafted on desized fabrics

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Summary

Introduction

Abstract: Interfacial bonding between the fibers and matrix plays a large role in mechanical properties of composites. Poly(oxypropylene) diamines (D400) and graphene oxide (GO) nanoparticles were grafted on the desized 3D multi axial warp knitted (MWK) glass fiber (GF) fabrics. Li et al [33,34,35] studied the tension fatigue behavior and failure mechanism of 3D MWK composites, and their tensile and bending properties at cryogenic temperature. Ma et al [36] added short glass fibers between MWK fabric layers to improve interface strength. GO nanoparticles were grafted on D400 grafted fibers in which flexible D400 acted as a bridge to improve the interface bonding between fiber and matrix, and further improve mechanical properties of MWK composites. The effect of D400 and GO nanoparticles on interface bonding of fiber/matrix were analyzed

Materials
Surface modifications of the 3D MWK fabrics
Characterization
Morphology of GF with D400 and GO nanoparticles
Compression stress-strain curves
Compression properties
Failure mechanism
Conclusions
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