The most hindered hydrotris(pyrazolyl)borate ligand, X-ray structure of chlorocopper(II) complex: [Cu(Cl){HB(3-Ad-5-Pr ipz) 3}] as compared with [Cu(Cl){HB(3-Bu t-5-Pr ipz) 3}

Kiyoshi Fujisawa,Naoki Tada,Yoko Ishikawa,Hideyuki Higashimura,Yoshitaro Miyashita,Ken-Ichi Okamoto

doi:10.1016/j.inoche.2003.10.030

The most hindered hydrotris(pyrazolyl)borate ligand, X-ray structure of chlorocopper(II) complex: [Cu(Cl){HB(3-Ad-5-Pr ipz) 3}] as compared with [Cu(Cl){HB(3-Bu t-5-Pr ipz) 3}

Kiyoshi Fujisawa, Naoki Tada + Show 4 more

https://doi.org/10.1016/j.inoche.2003.10.030

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Journal: Inorganic chemistry communications	Publication Date: Dec 2, 2003
Citations: 25

Affiliation: University of Tsukuba, Sumitomo Chemical (Japan)

#Borate Ligand #Spectroscopic Techniques + Show 2 more

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Abstract

Admantyl substituted hydrotris(pyrazolyl)borate ligand, which is the most hindered in all the hydrotris(pyrazolyl)borate ligands, is newly synthesized. Two chlorocopper(II) complexes with [HB(3-Ad-5-Pr i pz) 3] − and [HB(3-Bu t -5-Pr i pz) 3] − were characterized by X-ray diffraction and some spectroscopic techniques.

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