Abstract

We present results on the variation of 7.7 micron Polycyclic Aromatic Hydrocarbon (PAH) emission in galaxies spanning a wide range in metallicity at z ~ 2. For this analysis, we use rest-frame optical spectra of 476 galaxies at 1.37 < z < 2.61 from the MOSFIRE Deep Evolution Field (MOSDEF) survey to infer metallicities and ionization states. Spitzer/MIPS 24 micron and Herschel/PACS 100 and 160 micron observations are used to derive rest-frame 7.7 micron luminosities (L(7.7)) and total IR luminosities (L(IR)), respectively. We find significant trends between the ratio of L(7.7) to L(IR) (and to dust-corrected SFR) and both metallicity and [OIII]/[OII] (O32) emission-line ratio. The latter is an empirical proxy for the ionization parameter. These trends indicate a paucity of PAH emission in low metallicity environments with harder and more intense radiation fields. Additionally, L(7.7)/L(IR) is significantly lower in the youngest quartile of our sample (ages of 500 Myr) compared to older galaxies, which may be a result of the delayed production of PAHs by AGB stars. The relative strength of L(7.7) to L(IR) is also lower by a factor of ~ 2 for galaxies with masses $M_* < 10^{10}M_{\odot}$, compared to the more massive ones. We demonstrate that commonly-used conversions of L(7.7) (or 24 micron flux density; f(24)) to L(IR) underestimate the IR luminosity by more than a factor of 2 at $M_*$ ~ $10^{9.6-10.0} M_{\odot}$. We adopt a mass-dependent conversion of L(7.7) to L(IR) with L(7.7)/L(IR)= 0.09 and 0.22 for $M_* < 10^{10}$ and $> 10^{10} M_{\odot}$, respectively. Based on the new scaling, the SFR-$M_*$ relation has a shallower slope than previously derived. Our results also suggest a higher IR luminosity density at z ~ 2 than previously measured, corresponding to a ~ 30% increase in the SFR density.

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