Abstract
Abstract The molecular structure of the title compound has been determined from single-crystal X-ray diffraction methods. The molecule consists of an alkoxo-oxygen bridged dimeric unit, [Cu2{(CH3)2 N(CH2)3 NH(CH2)2O}2 (CH3OH)2]2+, and two perchlorate anions as counter ions. The coordination geometry of each copper ion is a five coordinated tetragonal pyramid, of which the apical site is occupied by the oxygen atom of methanol. The magnetic moment of the compound is remarkably higher than that expected from Cu[sbnd]O[sbnd]Cu angle. This is explained in terms of the effect of axial coordination.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
